A woman has died and three men have been injured in a head-on collision at Bruarong in the state's north east on Saturday.
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Ambulance Victoria spokesman John Mullen said paramedics were called to the crash on the Myrtleford-Yackandandah Road at 3.10pm.
Police say the female driver of a Toyota sedan was travelling south when she lost control and collided with a north-bound 4WD.
The woman, in her 30s, died at the scene.
JUST IN-Pictures of an accident on the Myrtleford- Yackandandah Road at #Bruarong @PRIME7Albury pic.twitter.com/7kWxrJUA69— Alexandra Ristway (@aristway27) June 25, 2016
The three occupants of the 4WD, two men in their 20s and a man in his 50s, suffered serious injuries.
One man, who was trapped with leg and pelvic injuries, is in a critical condition.
Another man suffered chest injuries and is in a serious but stable condition.
The third man suffered back injuries and is in a stable condition.
The three were taken to Albury Base Hospital.
Earlier on Saturday, a man and woman, aged 41 and 39, respectively, died when their car crashed into a tree at Daylesford, north west of Melbourne.
The Bruarong fatality brings the state's road toll to 145, 22 more than this time last year.